Biaxially Oriented Film -
Biaxially oriented polypropylene
(BOPP) film is film stretched in both machine and transverse
directions, producing molecular chain orientation in two directions.
BOPP film is produced by a tubular process, in which a tubular bubble is
inflated, or a tenter frame process, in which a thick extruded sheet is
heated to its softening point (not to the melting point) and is
mechanically stretched by 300–400%. Stretching in the tenter frame
process is usually 4.5:1 in the machine direction and 8.0:1 in the
transverse direction, although these ratios are fully adjustable. It is a
widely used process, more common than the tubular process, and a
glossy, transparent film is produced. Biaxial orientation results in
increased toughness, increased stiffness, enhanced clarity, improved oil
and grease resistance, and enhanced barrier properties to water vapor
and oxygen. Impact resistance, low-temperature impact resistance, and
flexcrack resistance are substantially modified. BOPP films are used in
food packaging and are replacing cellophane in applications such as
snack and tobacco packaging due to favorable properties and low cost (Fortilene Polypropylene Properties, Processing, and Design Manual, 1981; Goddard, 1993).
Oriented
films can be used as heat-shrinkable films in shrink-wrap applications
or can be heat set to provide dimensional stability. Heat sealing is
difficult in BOPP films, but can be made easier by either coating the
film after processing with a heat-sealable material (such as
polyvinylidene chloride) or by coextrusion with one or more copolymers
before processing to produce layers of film. Copolymers used in sealing
layers must have high gloss and clarity and should have low sealing
temperatures to prevent distortion of the oriented polymer during
sealing. Random copolymers containing 3–7% ethylene are often used as
sealing layers; the lower
melting point (<132°C; <270°F) results in a 30% increase in line
speeds, and they can be recycled with no significant loss of strength or
clarity. Coating or coextrusion increases the barrier properties of
BOPP film, decreasing its permeability to gases. Common barrier polymers
are ethylene vinyl alcohol, polyvinylidene chloride, and polyamide;
five or more layers may be coextruded or laminated, or the barrier
polymer can be dispersed in the matrix polymer (Fortilene Polypropylene Properties, Processing, and Design Manual, 1981; Goddard, 1993; Polymers in Contact with Food, 1991).