Biaxially Oriented Film -
Biaxially oriented polypropylene
 (BOPP) film is film stretched in both machine and transverse 
directions, producing molecular chain orientation in two directions. 
BOPP film is produced by a tubular process, in which a tubular bubble is
 inflated, or a tenter frame process, in which a thick extruded sheet is
 heated to its softening point (not to the melting point) and is 
mechanically stretched by 300–400%. Stretching in the tenter frame 
process is usually 4.5:1 in the machine direction and 8.0:1 in the 
transverse direction, although these ratios are fully adjustable. It is a
 widely used process, more common than the tubular process, and a 
glossy, transparent film is produced. Biaxial orientation results in 
increased toughness, increased stiffness, enhanced clarity, improved oil
 and grease resistance, and enhanced barrier properties to water vapor 
and oxygen. Impact resistance, low-temperature impact resistance, and 
flexcrack resistance are substantially modified. BOPP films are used in 
food packaging and are replacing cellophane in applications such as 
snack and tobacco packaging due to favorable properties and low cost (Fortilene Polypropylene Properties, Processing, and Design Manual, 1981; Goddard, 1993).
Oriented
 films can be used as heat-shrinkable films in shrink-wrap applications 
or can be heat set to provide dimensional stability. Heat sealing is 
difficult in BOPP films, but can be made easier by either coating the 
film after processing with a heat-sealable material (such as 
polyvinylidene chloride) or by coextrusion with one or more copolymers 
before processing to produce layers of film. Copolymers used in sealing 
layers must have high gloss and clarity and should have low sealing 
temperatures to prevent distortion of the oriented polymer during 
sealing. Random copolymers containing 3–7% ethylene are often used as 
sealing layers; the lower
 melting point (<132°C; <270°F) results in a 30% increase in line 
speeds, and they can be recycled with no significant loss of strength or
 clarity. Coating or coextrusion increases the barrier properties of 
BOPP film, decreasing its permeability to gases. Common barrier polymers
 are ethylene vinyl alcohol, polyvinylidene chloride, and polyamide; 
five or more layers may be coextruded or laminated, or the barrier 
polymer can be dispersed in the matrix polymer (Fortilene Polypropylene Properties, Processing, and Design Manual, 1981; Goddard, 1993; Polymers in Contact with Food, 1991).